Chalk it up to a single wardrobe selection that proved to be one sweet career move. It was a black Versace gown with gold safety pins that Elizabeth Hurley wore to the 1994 premiere of Four Weddings and a Funeral, arriving on the arm of the film's breakout star, Hugh Grant.

Everyone noticed the dress--and suddenly, finally, they noticed the woman wearing it.

While Liz Hurley's breakthrough can be traced back and pinned down to this particular fashion moment, it is only a fraction of her fascinating road to fame, as you'll find out in this striking episode Elizabeth Hurley: The E! True Hollywood Story. Of course, along the way, there are plenty of Bedazzling--and not so dazzling--moments.

The daughter of a British Army captain and a music teacher, Liz has come a long way from her ballerina beginnings and her days as a pink-haired punk. After studying at the London Studio Center, she nabbed parts in various university stage productions and then moved on to the title role in a BBC miniseries. Next came Hollywood, where she proved quite shagadelic opposite the International Man of Mystery himself.

There's no doubt, Hurley's a hottie. She once appeared on the cover of Tatler, and the issue became the biggest seller in the British fashion magazine's 285-year history.

This True Hollywood Story invites you along for a proper peek at this model turned actress turned producer turned mom.

But before we hurl headlong into the life of Hurley, find out if you're really an Elizabethan scholar with our Liz I.Q. Quiz.